I could see sailors using the rum to flavor their ration of tobacco, not use it to rehydrate it.Seafarers in the past used alcohol and salt to preserve all sorts of things, as lightweight air-tight packaging was difficult to achieve.
It's not at all unlikely that rum and other spirits were used to preserve bulk stores of tobacco, not that sailors used drops of their grog ration to rehydrate their own tobacco, which was also rationed and which they presumably wished to make last, and which was probably carried in nothing more than a cloth or leather pouch.