The water method worked perfectly!
Filled a 2cup Pyrex measuring cup with water, stuck it in the microwave, and clicked brew beverage, put the end of the stem that I wanted to "unbend" in the hot water for 15-20 seconds took it out and slightly straighten it out using only the slight pressure of my thumbs and fingers, and repeated this process 3-4 times going slowly and gently (pipe smokers should be all about the process not rushed results) until I got the shape that I wanted. and no discoloration occurred

Later tonight I'll post a pic of the pipe, but only the after results, didn't take one beforehand, but I'll try to indicate how it was bent by drawing a line