Superglue is an acrylic resin, meaning it dries glass-hard with no "give".
Vulcanite is countless tiny balls of rubber smooshed into a solid, meaning it does have "give".
Result? Tooth/bite compression of a pipe stem made from rubber which has an acrylic patch on it will cause the patch to flake, chip, and (eventually) detatch.
Mucher gooder is to use a type of epoxy called "G-Flex" that is formulated to have some elasticity.
Full usage info here:
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