I'm sure there are plenty of ways that work well. I've done several using this simple method.
1) bring a pot of water to a near boil
2) place stem in hot water for 3-5 minutes. With pipe cleaner inside stem.
3) remove wearing gloves and place over a round object. Glass, coffee can, etc.
4) submerge in cold water to set bend.
You will need to have the form ( glass, coffee can,) and the sink of cold water ready before removing the stem from the hot water. You have about a 30 second window before the vulcanite starts harden again. Place your thumb on the button end of stem and holding the opposite end, bend around your curved object of choice. Once it's shaped the way you want, continue holding slight pressure to keep the bend and dunk in the cold water for 30-45 seconds. Once cooled, it's locked into that shape unless you repeat the process. I haven't used a heat gun or candle but the hot water gives a uniformly heated stem to work with.