Mind you, I have no experience with horn, but when I’ve had very stubborn vulcanite stingers here’s what I’ve done:
Fold a sheet of aluminum foil to about a 2” multi thickness square, then poke a stinger sized hole in center. Slide square as a shield/heat sink over stinger and applied stinger directly to a heat source (I’ve got an old school electric stove with exposed elements) to loosen glue.
I use pliers padded with leather to grasp and twist stinger.
Thus worked well to heat stinger and protected the sharp corners I didn’t want to soften from the radiant heat.
Good luck, be patient and careful.